Poly[diaqua(μ-4,4′-bipyridine-κ2 N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ2 O:O′]cadmium]
نویسنده
چکیده
In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water mol-ecules and two bridging 2,2'-(μ-p-phenyl-enedi-oxy)diacetate ligands and two N atoms from two 4,4'-bipyridine ligands, giving a slightly distorted octa-hedral geometry. The diacetate and 4,4'-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Formula: see text]), with adjacent layers inter-connected via O-H⋯O hydrogen bonds between the coordinated water mol-ecules and the carboxyl-ate O atoms, giving a three-dimensional supra-molecular architecture.
منابع مشابه
catena-Poly[[diaqua[(4-tolylsulfanyl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ2 N:N′]
The title complex, [Cd(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), has a linear chain structure. The central Cd(II) ion is in a slightly disorted octa-hedral environment, coordinated by two aqua ligands, two (4-tolyl-sulfan-yl)acetate ligands and two bridging 4,4'-bipyridine ligands. The Cd(II) ion lies on a twofold rotation axis. Inter-molecular O-H⋯O hydrogen bonds connect adjacent chains...
متن کاملcatena-Poly[[diaqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-2,2′-[1,4-phenylenebis(sulfanediyl)]diacetato-κ2 O:O′]
In the polymeric title complex, [Zn(C(10)H(8)O(4)S(2))(C(10)H(8)N(2))(H(2)O)(2)](n), the Zn(2+) ion lies on a twofold rotation axis and exhibits an octa-hedral environment, in which it is coordinated by two trans O atoms from two symmetry-related 2,2'-[1,4-phenyl-enebis(sulfanedi-yl)]diacetate anions, two N atoms from one 2,2'-bipyridine ligand, and two cis O atoms from water mol-ecules. The di...
متن کاملcatena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ2 O:O′]
In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxyl-ate groups of two different 2,2'-(p-phenyl-enedi-oxy)diacetate ligands, two N atoms from two pyridine mol-ecules and one water O atom. The geometry is square-pyramidal with the water O atom occupying the apical position. The carboxyl-ate group bridges adjacent Cu ...
متن کاملPoly[[μ-aqua-bis(μ-4,4′-bipyridine-κ2 N:N′)bis(μ-3-hydroxyadamantane-1-carboxylato-κ2 O:O′)bis(3-hydroxyadamantane-1-carboxylato-κO)dicobalt(II)] heptahydrate]
The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy-droxy-adamantane-1-carboxyl-ate anions (L), one water mol-ecule, two bridging 4,4'-bipyridine (4,4'-bpy) ligands and seven uncoordinated water mol-ecules. Both of the Co(II) ions are coordinated in a distorted octa-hedral geometry. Four L ligands bind to e...
متن کاملcatena-Poly[[copper(I)-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-2,2′-bipyridine-κ2 N:N′] bis(tetrafluoridoborate) dichloromethane 2.5-solvate]
The title complex, {[Cu(2)(C(10)H(8)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)·2.5CH(2)Cl(2)}(n), contains chains of Cu(I) centres bridged alternately by two (diphenyl-phosphino)methane (dppm) and 4,4'-bipyridine (bpy) ligands. Each Cu(I) atom is coordinated by one N atom of 4,4'-bipyridine (bpy) and two P atoms of two (diphenyl-phosphino)methane (dppm) ligand, and has a trigonal-planar coordination g...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011